This is the call which should show the dialog. It is inside a conditional statement. Have you put a breakpoint there to test whether the code actually gets there?
Var Open_Dlg As New OpenFileDialog
Var FI_Video_Movie As FolderItem
Open_Dlg.Filter = "VideoMP4"
Open_Dlg.PromptText = "Das mp4-Video aussuchen."
Open_Dlg.Title = "Bitte das Video öffnen"
Open_Dlg.Left = 50
Open_Dlg.Top = 50
Open_Dlg.ActionButtonCaption = "OK"
Open_Dlg.CancelButtonCaption = "Abbruch"
'If Pfad_zur_Filmdatei = "" Then
FI_Video_Movie = Open_Dlg.ShowModal
If FI_Video_Movie<>Nil And FI_Video_Movie.exists Then
MessageBox "Valid file Reference"
'Videofenster.ThePlayer.movie=Movie.Open(App.FI_Video_Movie)
End If
'App.Pfad_zur_Filmdatei=App.FI_Video_Movie.NativePath